(2018) Voltammetric Determination of Droxidopa in the Presence of Tryptophan Using a Nanostructured Base Electrochemical Sensor. Journal of Electrochemical Science and Technology. pp. 109-117. ISSN 2093-8551
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Abstract
A novel carbon paste electrode modified with Cu-TiO2 nanocomposite, 2-(ferrocenylethynyl)fluoren-9-one (2FF) and ionic liquid (IL) (2FF/Cu-TiO2 /IL/CPE) was fabricated and employed to study the electrocatalytic oxidation of droxidopa, using cyclic voltammetry (CV), chronoamperometry (CHA) and differential pulse voltammetry (DPV) as diagnostic techniques. It has been found that the oxidation of droxidopa at the surface of modified electrode occurs at a potential of about 295 mV less positive than that of an unmodified CPE. DPV exhibits a linear dynamic range from 5.0 x 10(-8) to 4.0 x 10(-4) M and a detection limit of 30.0 nM for droxidopa. Finally this modified electrode was used for simultaneous determination of droxidopa and tryptophan. Also the 2FF/Cu-TiO2 /IL/CPE shows excellent ability to determination of droxidopa and tryptophan in real samples.
Item Type: | Article |
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Keywords: | Droxidopa Tryptophan Ionic liquid Carbon paste electrode Cu-TiO2 nanocomposite 2-(ferrocenyl-ethynyl)fluoren-9-one carbon-paste electrode ionic liquids photocatalytic activity selective determination graphene oxide norepinephrine acetaminophen nanotubes isoproterenol nanocomposite Electrochemistry |
Divisions: | |
Page Range: | pp. 109-117 |
Journal or Publication Title: | Journal of Electrochemical Science and Technology |
Journal Index: | ISI |
Volume: | 9 |
Number: | 2 |
Identification Number: | https://doi.org/10.5229/jecst.2018.9.2.109 |
ISSN: | 2093-8551 |
Depositing User: | مهندس مهدی شریفی |
URI: | http://eprints.mubam.ac.ir/id/eprint/548 |
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