Abstract

In this study, Cu and Zn-metal organic framework nanostructures were synthesized in the shortest possible time and with high efficiency using the ultrasonic assisted reverse micelle (UARM) method. Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, and nitrogen adsorption techniques were used to characterize the synthesized samples. According to the BET method, the Cu-MOF sample has 410 m(2)/g of surface area and a volume pore of 0.021 cm(3), whereas the corresponding values for Zn-MOF were 1145 m(2)/g and 0.097 cm(3), respectively. The physicochemical properties of the products were thoroughly investigated, and the adsorbent dosage, temperature, and pressure for preparing samples with experimental parameters were 0.05 mg, 25.0 degrees C and 5.0 bar, respectively with high adsorption efficiency. Fractional factorial design and response surface methodology were used to design and control the best conditions. It could be used as an adsorbent in the adsorption of arsine gas.